助理教授 (副研究员) 化学系   课题组网站

2020年9月加入南方科技大学化学系,任助理教授(副研究员)、独立课题组长、博士生导师。

2007年至2016年在厦门大学化学系攻读学士(2007—2011)和博士(2011—2013, 2015—2016)学位,并于2016年获得有机化学博士学位,师从中国科学院院士赵玉芬教授。2013年至2015年,在加州大学圣地亚哥分校学习无机化学(博士研究生联合培养,国家留学基金委资助),师从法国科学院院士Guy Bertrand教授。

博士毕业后在加拿大多伦多大学(2016—2019;合作导师为加拿大皇家科学院院士Douglas W. Stephan教授)和美国劳伦斯伯克利国家实验室与加州大学伯克利分校(2019—2020;合作导师为三位美国科学院院士F. Dean Toste教授、Kenneth N. Raymond教授和Robert G. Bergman教授)从事博士后科研工作。

截至2021年6月,在国际知名期刊共发表学术论文60余篇(h-index: 28),授权专利一项。担任《Chem》期刊青年编委(Next-Generation Advisors)(2020—)和《EurJIC》青年编委(Early Career Advisory Board Member)(2022—)。研究领域为基于主族元素的有机化学、无机化学和理论计算化学。入选深圳市海外高层次“孔雀计划”B类人才(2021)。

个人简介

研究领域

主族元素有机/无机化学


教学

化学原理A

化学原理B


学术成果 查看更多

For full publications, please see: https://www.liuleoliu.com/overview-publications

Representative publications:

At SUSTech:

3) X. Zhang and L. L. Liu,* A Free Aluminylene with Diverse σ-Donating and Doubly σ/π-Accepting Ligand Features for Transition MetalsAngew. Chem. Int. Ed. in press.

2) S. Li; C. Hu; X. Cui; J. Zhang; L. L. Liu* and L. Wu,* Site-Fixed Hydroboration of Terminal and Internal Alkenes Using BX3/iPr2NEtAngew. Chem. Int. Ed. 202160, XXXX-XXXX.

1) R. Guo; T. Li; R. Wei; X. Zhang; Q. Li; L. L. Liu;* C. Tung and L. Kong,* Boraiminolithium: An Iminoborane-Transfer ReagentJ. Am. Chem. Soc. 2021143, 13483–13488. (Highlighted by ChemistryViews)

Before SUSTech:

1) L. Liu; D. A. Ruiz; D. Munz and G. Bertrand,* A Singlet Phosphinidene Stable at Room Temperature, Chem 20161, 147–153. (Highlighted by Chem. Eng. News entitled “Stable phosphorus carbene analog debuts”; Previewed by Rory Waterman entitled “A ‘Bottle-able’ Phosphinidene” in Chem)

2) L. L. Liu; L. L. Cao; Y. Shao; G. Ménard and D. W. Stephan,* A Radical Mechanism for Frustrated Lewis Pair Reactivity, Chem 20173, 259–267. (Highlighted by front cover; Previewed by Duncan F. Wass entitled “How Important Are Radical Mechanisms in Frustrated Lewis Pair Chemistry?” in Chem)

3) L. L. Liu; L. L. Cao; Y. Shao and D. W. Stephan,* Single Electron Delivery to Lewis Pairs: An Avenue to Anions by Small Molecule Activation, J. Am. Chem. Soc. 2017139, 10062–10071.

4) L. L. Liu; J. Zhou; L. L. Cao; R. Andrews; R. L. Falconer; C. A. Russell and D. W. Stephan,* A Transient Vinylphosphinidene via a Phosphirene−Phosphinidene Rearrangement, J. Am. Chem. Soc. 2018140, 147–150.

5) L. L. Liu; J. Zhou; R. Andrews and D. W. Stephan,* A Room-Temperature-Stable Phosphanorcaradiene, J. Am. Chem. Soc. 2018140, 7466–7470.

6) L. L. Liu; J. Zhou; L. L. Cao; Y. Kim and D. W. Stephan,* Reversible Intramolecular Cycloaddition of Phosphaalkene to an Arene Ring, J. Am. Chem. Soc. 2019141, 8083–8087.

7) L. L. Liu; J. Zhou; L. L. Cao and D. W. Stephan,* Phosphaaluminirenes: Synthons for Main Group Heterocycles, J. Am. Chem. Soc. 2019141, 16971–16982. (Highlighted by ChemistryViews entitled “Phosphaaluminirenes Synthesized”)

8) L. L. Liu; L. L. Cao; J. Zhou and D. W. Stephan,* Facile Cleavage of the P=P Double Bond in Vinyl-Substituted Diphosphenes, Angew. Chem. Int. Ed. 2019, 58, 273–277.

9) J. Tang;+ L. L. Liu;+ S. Yang;+ X. Cong; M. Luo and X. Zeng,* Chemoselective Cross-Coupling between Two Different and Unactivated C(aryl)–O Bonds Enabled by Chromium Catalysis, J. Am. Chem. Soc. 2020142, 7715–7720. (+ = equal contribution)

10) X. Chen;+ L. L. Liu;+ S. Liu; H. Grützmacher and Z. Li,* A Room-Temperature Stable Distonic Radical Cation, Angew. Chem. Int. Ed. 202059, 23830-23835. (+ = equal contribution)

11) L. L. Liu; D. A. Ruiz; F. Dahcheh; G. Bertrand;* R. Suter; A. M. Tondreau and H. Grützmacher,* Isolation of Au-, Co-η1 PCO and Cu-η2 PCO Complexes, Conversion of an Ir-η1 PCO Complex into a Dimetalladiphosphene, and an Interaction-free PCO Anion, Chem. Sci. 20167, 2335–2341.

12) L. L. Liu,* The Dynamic Nature of Phosphorus, Chem 20173, 195–197. (Invited “Potential Energy” article)

13) L. L. Liu and D. W. Stephan,* Radicals Derived from Lewis Acid/Base Pairs, Chem. Soc. Rev. 201948, 3454–3463.

14) L. L. Liu; J. Zhu* and Y. Zhao,* The Phosphaethynolate Anion Reacts with Unsaturated Bonds: DFT Investigations on [2+2], [3+2] and [4+2] Cycloadditions, Chem. Comm. 201450, 11347–11349.

15) L. L. Liu; D. A. Ruiz; F. Dahcheh and G. Bertrand,* Isolation of a Lewis Base Stabilized Parent Phosphenium (PH2+) and Related Species, Chem. Comm. 201551, 12732–12735.

16) L. L. Liu and D. W. Stephan,* An Imine-Gallium Lewis Pair Stabilized Oxophosphinidene via an Unexpected Phosphirene Rearrangement, Chem. Comm. 201854, 1041–1044. (Highlighted by front cover)

17) L. L. Liu; L. L. Cao; D. Zhu; J. Zhou and D. W. Stephan,* Homolytic Cleavage of Peroxide Bonds via a Single Electron Transfer of Frustrated Lewis Pair, Chem. Comm. 201854, 7431–7434. (Highlighted by front cover)

18) Y. Wu;* C. Shan; Y. Sun; P. Chen; J. Ying; J. Zhu; L. L. Liu* and Y. Zhao,* Main Group Metal Ligand Cooperation of N-Heterocyclic Germylene: An Efficient Catalyst for the Hydroboration of Carbonyl Compounds, Chem. Comm. 201652, 13799–13802.

19) Y. Wu; L. L. Liu;* J. Su; J. Zhu; Z. Ji and Y. Zhao,* Isolation of a Heavier Cyclobutadiene Analogue: 2,4-Digerma-1,3-diphosphacyclobutadiene, Organometallics, 201635, 1593–1596.

20) J. Zhou; L. L. Liu; L. L. Cao and D. W. Stephan,* The η5-Pentamethylcyclopentadienyl Phosphorus Dication [(η5-Cp*)P]2+: A Phosphorus Lewis Super Acid, Chem 20184, 2699–2708. (Highlighted by Chemistryworld entitled “Rare phosphorus dication synthesised”)

21) Z. Li;* X. Chen; L. L. Liu; M. T. Scharnhölz and H. Grützmacher,* N-Heterocyclic Carbene Stabilized Dicarbondiphosphide: A Strong Neutral Four-membered Heterocyclic 6π-electron Donor, Angew. Chem. Int. Ed. 202059, 4288–4293.

22) J. Zhou; L. L. Liu; L. L. Cao and D. W. Stephan,* Base-Stabilized [PO]+/[PO2]+ Cations, Angew. Chem. Int. Ed. 201958, 18276–18280.

23) J. Zhou; L. L. Liu; L. L. Cao and D. W. Stephan,* The Arene-Stabilized η5-Pentamethylcyclopentadienyl Arsenic Dication [(η5-Cp*)As(toluene)]2+, Angew. Chem. Int. Ed. 201958, 5407–5412.

24) J. Zhou; L. L. Liu; L. L. Cao and D. W. Stephan,* Nitrogen-Based Lewis Acids: Synthesis and Reactivity of a Cyclic (Alkyl)(Amino)Nitrenium Cation, Angew. Chem. Int. Ed. 201857, 3322–3326.

25) C. Pranckevicius; L. L. Liu; G. Bertrand and D. W. Stephan,* Synthesis of a Carbodicyclopropenylidene: A Carbodicarbene Based Solely on Carbon, Angew. Chem. Int. Ed. 201655, 5536–5540.

26) Z. Li; X. Chen; Z. Benkő; L. L. Liu; D. Ruiz; J. Peltier; G. Bertrand;* C. Su* and H. Grützmacher,* N-Heterocyclic Carbenes as Promotors for the Rearrangement of Phosphaketenes to Phosphaheteroallenes: A Case Study for OCP to OPC Constitutional Isomerism, Angew. Chem. Int. Ed. 201655, 6018–6022.

27) B. Rao; H. Tang; X. Zeng*; L. L. Liu; M. Melaimi and G. Bertrand,* Cyclic (Amino)(aryl)carbenes (CAArCs) as Strong σ-Donating and π-Accepting Ligands for Transition Metals, Angew. Chem. Int. Ed. 201554, 14915–14919.

28) C. Weinstein; C. Martin; L. L. Liu and G. Bertrand,* Cross-Coupling Reactions between Stable Carbenes, Angew. Chem. Int. Ed. 201453, 6550–6553.

29) M. M. Hansmann; D. A. Ruiz; L. L. Liu; R. Jazzar and G. Bertrand,* (Phosphanyl)phosphaketenes as Building Blocks for Novel Phosphorus Heterocycles, Chem. Sci. 2017, 8, 3720-3725.

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