RA ZHANG Shilong

2019-11-12

transition metal catalysis

2019.4-2019.12

 

Journal Papers

 A panel of natural aliphatic tertiary alkaloids (R3N) were directly converted to R3N+–NH (without the need to prepare protected aminimides R3N+–NR′ followed by deprotection) by [Mn(TDCPP)Cl]-catalysed N-amination reaction, with O-(2,4-dinitrophenyl)hydroxylamine as the nitrogen source, in up to 98% yields under mild reaction conditions. (Chemical Communications 202056, 9102–9105.  DOI: 10.1039/D0CC02934C)