Publications in Sustech：

(37) Zu, B.; Guo, Y.; He, C.*

Catalytic Enantioselective Construction of Chiroptical Boron-Stereogenic Compounds, 

J. Am. Chem. Soc. 2021, 143, 16302–16310. https://doi.org/10.1021/jacs.1c08482

Highlight by "X-mol"：https://mp.weixin.qq.com/s/87t75bqkiO45h9AkHzZfoQ

(36) Liu, W.; Ke, J.; He, C.*

Sulfur Stereogenic Centers in Transition-Metal-Catalyzed Asymmetric C–H Functionalization: Generation and Utilization (Perspective), 

Chem. Sci. 2021, 12, 10972−10984. https://doi.org/10.1039/D1SC02614C

(35) You, L.; Yuan, W.; He, C.* 

Intermolecular Dehydrogenative C−H/Si−H Cross-Coupling for the Synthesis of Arylbenzyl Bis(silanes), 

Eur. J. Org. Chem. 2021, 3079–3082. https://doi.org/10.1002/ejoc.202100474

Special Collection on "Silicon Chemistry in Organic Synthesis"

Highlight by ChemistryViews：https://www.chemistryviews.org/details/ezine/11301891/Access_to_Arylbenzyl_Bissilanes.html

Highlight by "WileyChem"：https://mp.weixin.qq.com/s/TgZV0BMr4f3mae5jNEtIzQ

(34) Zhu, J.; He, C.* 

Catalytic Enantioselective Synthesis of Silicon-Stereogenic Alkoxysilanes and Siloxanes (Invited Synpacts),

Synlett 2021, 32, 1575–1580. DOI: 10.1055/a-1503-7976

Highlight by "CBG"：https://mp.weixin.qq.com/s/tUW-qSNypqDzwHnWIT-4FQ

(33) Guo, Y.; Liu, M.-M.; Zhu, X.; Zhu, L.; He, C.* 

Catalytic Asymmetric Synthesis of Silicon-Stereogenic Dihydrodibenzosilines: Silicon-Central to Axial Chirality Relay, 

Angew. Chem., Int. Ed. 2021, 60, 13887−13891. https://doi.org/10.1002/anie.202103748

Highlight by "WileyChem"：https://mp.weixin.qq.com/s/r2GiWG-Jmtu_NnAAPldFiQ

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(32) Zhu, J.; Chen, S.; He, C.* 

Catalytic Enantioselective Dehydrogenative Si–O Coupling to Access Chiroptical Silicon-Stereogenic Siloxanes and Alkoxysilanes, 

J. Am. Chem. Soc. 2021, 143, 5301−5307. https://doi.org/10.1021/jacs.1c01106

Highlight by "X-mol"：https://mp.weixin.qq.com/s/bHwowbqOCBpc9U44gVa-sg

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(31) Ke, J.; Liu, W.; Zhu, X.; Tan, X.; He, C.* 

Electrochemical Radical Silyl-Oxygenation of Activated Alkenes, 

Angew. Chem., Int. Ed. 2021, 60, 8744−8749. https://doi.org/10.1002/anie.202016620

Highlight by "WileyChem"：https://mp.weixin.qq.com/s/4IoPnNv_Wa8XdkwUPR9OSw

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(30) Zu, B.; Guo, Y.; Ke, J.; He, C.*

Transient and Native Directing Group Enabled Enantioselective C–H Functionalization (Invited Short Review),

Synthesis 2021, 53, 2029–2042. DOI: 10.1055/a-1372-6627

(29) Yuan, W.; You, L.; Lin, W.; Ke, J.; Li, Y.; He, C.*

Asymmetric Synthesis of Silicon-Stereogenic Monohydrosilanes by Dehydrogenative C–H Silylation,

Org. Lett. 2021, 23, 1367−1372. http://dx.doi.org/10.1021/acs.orglett.1c00029

Highlight by "CBG"：https://mp.weixin.qq.com/s/mQzFs4aWuwdhOZJUw6nJMQ

(28) Chen, S.; Mu, D.; Mai, P-L.; Ke, J.; Li, Y.; He, C.*

Enantioselective Construction of Six- and Seven-Membered Triorgano-Substituted Silicon-Stereogenic Heterocycles,

Nat. Commun. 2021, 12, 1249. https://doi.org/10.1038/s41467-021-21489-6

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(27) Ke, J.; Zu, B.; Guo, Y.; Li, Y.; He, C.*

Hexafluoroisopropanol-Enabled Copper-Catalyzed Asymmetric Halogenation of Cyclic Diaryliodoniums for the Synthesis of Axially Chiral 2,2'-Dihalobiaryls,

Org. Lett. 2021, 23, 329−333. http://dx.doi.org/10.1021/acs.orglett.0c03833

Highlight by "Organic Chemistry Portal"：https://www.organic-chemistry.org/abstracts/lit7/723.shtm

(26) Zu, B.; Ke, J.; Guo, Y.; He, C.*

Synthesis of Diverse Aryliodine(III) Reagents by Anodic Oxidation,

Chin. J. Chem. 2021, 39, 627−632. https://doi.org/10.1002/cjoc.202000501

"special issue dedicated to Department of Chemistry, SUSTech, on the occasion of her 10th founding anniversary" in Chinese Journal of Chemistry.

(25) Yang, W.; Li, Y.; Zhu, J.; Liu, W.; Ke, J.; He, C.*

Lewis Acid-Assisted Ir(III) Reductive Elimination Enables Construction of Seven-Membered-Ring Sulfoxides, 

Chem. Sci. 2020, 11, 10149−10158. https://doi.org/10.1039/D0SC04180G

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(24) Yang, B.; Yang, W.; Guo, Y.; You, L.; He, C.* 

Enantioselective Silylation of Aliphatic C–H Bonds for the Synthesis of Silicon-Stereogenic Dihydrobenzosiloles, 

Angew. Chem., Int. Ed. 2020, 59, 22217−22222. https://doi.org/10.1002/anie.202009912

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(23) Mu, D.; Yuan, W.; Chen, S.; Wang, N.; Yang, B.; You, L.; Zu, B.; Yu, P.; He, C.*

Streamlined Construction of Silicon-Stereogenic Silanes by Tandem Enantioselective C−H Silylation/Alkene Hydrosilylation, 

J. Am. Chem. Soc. 2020, 142, 13459−13468. https://doi.org/10.1021/jacs.0c04863

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(22) Liu, W.; Yang, W.; Zhu, J.; Guo, Y.; Wang, N.; Ke, J.; Yu, P.; He, C.* 

Dual Ligand Enabled Ir(III)-Catalyzed Enantioselective C–H Amidation for the Synthesis of Chiral Sulfoxides, 

ACS Catal. 2020, 10, 7207−7215. https://doi.org/10.1021/acscatal.0c02109

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(21) He, C.*; Whitehurst, W. G.; Gaunt, M. J.*

Palladium-Catalyzed C(sp³)–H Bond Functionalization of Aliphatic Amines, 

Chem. 2019, 5, 1031–1058. https://doi.org/10.1016/j.chempr.2018.12.017

(20) He, C.*  

Oxidative Coupling Reactions Between Hydrocarbons and Organometallic Reagents (The Second Generation). In: Lei A. (eds) Transition Metal Catalyzed Oxidative Cross-Coupling Reactions. Lecture Notes in Chemistry, vol 102. Springer, Berlin, Heidelberg, 2019.

https://doi.org/10.1007/978-3-662-58104-9_3

Ph.D. and Postdoc Publications：

(19) Nappi, M.; He, C. (co-first author); Whitehurst, W. G.; Chappell, B. G. N.; Gaunt, M. J.

Selective Reductive Elimination at Alkyl Pd(IV) via Dissociative Ligand Ionization Enables Catalytic C(sp³)–H Amination to Azetidines, 

Angew. Chem., Int. Ed. 2018, 57, 3178–3182. https://doi.org/10.1002/anie.201800519

(18) He, C.; Gaunt, M. J.

Ligand-Assisted Palladium-Catalyzed C–H Alkenylation of Aliphatic Amines for the Synthesis of Functionalized Pyrrolidines, 

Chem. Sci. 2017, 8, 3586–3592. http://dx.doi.org/10.1039/C7SC00468K

(17) He, C.* 

Chapter 3 Oxidative Couplings Involving the Cleavage of C–H Bonds. In Lei, A.; Shi, W.; Liu, C.; Liu, W.; Zhang, H.; He, C. Oxidative Cross-Coupling Reactions; Wiley-VCH Verlag GmbH & Co. KGaA: 2016.

https://doi.org/10.1002/9783527680986.ch3

(16) He, C.; Gaunt, M. J.

Ligand-Enabled Catalytic C–H Arylation of Aliphatic Amines by a Four-Membered-Ring Cyclopalladation Pathway, 

Angew. Chem., Int. Ed. 2015, 54, 15840–15844. https://doi.org/10.1002/anie.201508912

(15) He, C.; Lei, A.

Application of Nontoxic Iron Salts in Oxidative C–C Coupling Reactions in Comprehensive Inorganic Chemistry II, eds. Reedijk, J. and Poeppelmeier, K., Vol 6. Oxford: Elsevier; 2013. p. 521–547.

https://doi.org/10.1016/B978-0-08-097774-4.00619-7

(14) Ke, J.; He, C. (co-first author); Liu, H.; Li, M.; Lei, A.

Oxidative Cross-Coupling /Cyclization to Build Polysubstituted Pyrroles from Terminal Alkynes and b-Enamino Esters, 

Chem. Commun. 2013, 49, 7549–7551. http://dx.doi.org/10.1039/C3CC43682A

(13) Ke, J.; He, C. (co-first author); Liu, H.; Xu, H.; Lei, A.

Alcohol Assisted C–C Bond Breaking: Copper-Catalyzed Deacetylative a-Arylation of b-keto Esters and Amides, 

Chem. Commun. 2013, 49, 6767–6769. http://dx.doi.org/10.1039/C3CC43279C

(12) Gao, M.; He, C. (co-first author); Chen, H.; Bai, R.; Cheng, B.; Lei, A.

Synthesis of Pyrroles by Click Reaction: Silver-Catalyzed Cycloaddition of Terminal Alkynes with Isocyanides, 

Angew. Chem., Int. Ed. 2013, 52, 6958–6961. https://doi.org/10.1002/anie.201302604 

(11) He, C.; Ke, J.; Xu, H.; Lei, A.

Synergistic Catalysis in the Sonogashira Coupling Reaction: Quantitative Kinetic Investigation of Transmetalation, 

Angew. Chem., Int. Ed. 2013, 52, 1527–1530. https://doi.org/10.1002/anie.201207970

(10) He, C.; Zhang, G.; Ke, J.; Zhang, H.; Miller, J. T.; Kropf, A. J.; Lei, A.

Labile Cu(I)-Catalyst/Spectator Cu(II)-Species in Copper-Catalyzed C–C Coupling Reaction: Operando IR, In situ XANES/EXAFS Evidence and Kinetic Investigations, 

J. Am. Chem. Soc. 2013, 135, 488–493. https://doi.org/10.1021/ja310111p

(9) He, C.; Guo, S.; Ke, J.; Hao, J.; Xu, H.; Chen, H.; Lei, A.

Silver-Mediated Oxidative C–H/C–H Functionalization: A Strategy To Construct Polysubstituted Furans, 

J. Am. Chem. Soc. 2012, 134, 5766–5769. https://doi.org/10.1021/ja301153k

(8) He, C.; Hao, J.; Xu, H.; Mo, Y.; Liu, H.; Han, J.; Lei, A.

Heteroaromatic imidazo[1,2-a]pyridines synthesis from C–H/N–H oxidative cross-coupling/cyclization, 

Chem. Commun. 2012, 48, 11073–11075. http://dx.doi.org/10.1039/C2CC35927H

(7) He, C.; Guo, S.; Huang, L.; Lei, A.

Copper Catalyzed Arylation/C–C Bond Activation: An Approach toward alpha-Aryl Ketones, 

J. Am. Chem. Soc. 2010, 132, 8273–8275. https://doi.org/10.1021/ja1033777

(6) He, C.; Chen, C.; Cheng, J.; Liu, C.; Liu, W.; Li, Q.; Lei, A.

Aryl halide tolerated electrophilic amination of arylboronic acids with N-chloroamides catalyzed by CuCl at room temperature, 

Angew. Chem., Int. Ed. 2008, 47, 6414–6417. https://doi.org/10.1002/anie.200801427

(5) Cheng, B.; Yi, H.; He, C.; Liu, C.; Lei, A.

Revealing the Ligand Effect on Copper(I) Disproportionation via Operando IR Spectra, 

Organometallics 2015, 34, 206–211. https://doi.org/10.1021/om501053k

(4) Weng, Y.; Cheng, B.; He, C.; Lei, A.

Rational Design of a Pd-Catalyzed C_sp–C_sp Cross-Coupling Reaction Inspired by Kinetic Studies, 

Angew. Chem., Int. Ed. 2012, 51, 9547–9551. https://doi.org/10.1002/anie.201204112

(3) Liu, W.; Cao, H.; Zhang, H.; Zhang, H.; Chung, K. H.; He, C.; Wang, H.; Kwong, F. Y.; Lei, A.

Organocatalysis in Cross-Coupling: DMEDA-Catalyzed Direct C–H Arylation of Unactivated Benzene, 

J. Am. Chem. Soc. 2010, 132, 16737–16740. https://doi.org/10.1021/ja103050x

(2) Yin, W.; He, C.; Chen, M.; Zhang, H.; Lei, A.

Nickel-catalyzed oxidative coupling reactions of two different terminal alkynes using O₂ as the oxidant at room temperature: facile syntheses of unsymmetric 1,3-diynes, 

Org. Lett. 2009, 11, 709–712. https://doi.org/10.1021/ol8027863

(1) Liu, C.; He, C.; Shi, W.; Chen, M.; Lei, A.

Ni-catalyzed mild arylation of alpha-halocarbonyl compounds with arylboronic acids, 

Org. Lett. 2007, 9, 5601–5604. https://doi.org/10.1021/ol702456z