Publications

  • Journal Papers
  • Invention Patent

1. [(NHC)NiIIH]-Catalyzed Cross-Hydroalkenylation of Cyclopropenes with Alkynes: Cyclopentadiene Synthesis by [NHC-NiII]-Assisted C-C Rearrangement.
Huang, J.-Q.; Ho, C.-Y.* Angew. Chem. Int. Ed. 2019, 58, 5702.
2. Synthesis and Study of Au(III)-Indolizine Derivatives: Turn-on Luminescence by Photo-induced Control Release.
Yang, J.; Zhu, Y.; Tse, A. K.-W.; Zhou, X.; Chen, Y.; Tse, Y. C.;* Wong, K. M.-C.;* Ho, C.-Y.* Chem. Commun. 2019, 55, 4471
3. (NHC)NiH-Catalyzed Regiodivergent Cross-Hydroalkenylation of Vinyl Ether with α-Olefin: 1,2- and 1,3-Disubstituted Allyl Ether Syntheses.
Chen, W.; Li, Y.; Chen, Y.; Ho, C.-Y.* Angew. Chem. Int. Ed. 2018, 57, 2677.
4. (NHC)NiH-Catalyzed Intermolecular Regio- and Diastereoselective Cross-Hydroalkenylation of Endocyclic Dienes with α-Olefins.
Lian, X.; Chen, W.; Dang, L.; Li, Y.; Ho, C.-Y.* Angew. Chem. Int. Ed. 2017, 56, 9048.
5. Catalytic Asymmetric Hydroalkenylation of Vinylarenes: Electronic Effects of Substrates and Chiral N-Heterocyclic Carbene Ligands
Ho, C.-Y.*; Chan, C.-W.; He, L. Angew. Chem. Int. Ed. 2015, 54, 4512.
6. Substituted 1,3-cyclohexadiene synthesis by NHC-Nickel(0) catalyzed [2+2+2] cycloaddition of 1,n-Enyne”.
Zhao, J.-P.; Chan, S.-C.; Ho, C.-Y.* Tetrahedron 2015, 71, 4426.
7. Medium-Sized Heterocycle Synthesis by the Use of Synergistic Effects of Ni-NHC and γ‑Coordination in Cycloisomerization.
Ho, C.-Y.*; He, L. J. Org. Chem. 2014, 79, 11873.
8. Nitrate-Enhanced NHC-NiH Catalyzed Tail-to-Tail Vinyl Ether Dimerization.
He, L.; Ho, C.-Y.* Synlett 2014, 25, 2738.
9. Shuffle off the Classic -Si Elimination by Ni-NHC Cooperation:
Implication for C-C Forming Reactions Involving Ni-Alkyl-β-Silanes.
Ho, C.-Y.*; He, L. Chem. Commun. 2012, 48, 1481.
10. Catalytic Intermolecular Tail-to-Tail Hydroalkenylation of Styrenes with alpha Olefins: Regioselective Migratory Insertion Controlled by a Nickel/N-Heterocyclic Carbene.
Ho, C.-Y.*; He, L. Angew. Chem. Int. Ed. 2010, 49, 9182.
11. Cyanative Alkene-Aldehyde Coupling: Ni(0)-NHC-Et2AlCN Mediated Chromanols Synthesis with High cis-Selectivity at room temperature.
Ho, C.-Y.* Chem. Commun. 2010, 46, 466.
12. Nitrile assisted, Bronsted acid catalyzed regio and stereoselective diarylphosphonylation of allyl silyl ethers.
Ho, C.-Y.*; Chan, C.-W.; Wo, S.-K.; Zuo, Z.; Chan, L.-Y. Org. Biomol. Chem. 2010, 8, 3480.
13. Alpha Olefins as Alkenylmetal Equivalents in Catalytic Conjugate Addition Reactions.
Ho, C.-Y.; Ohmiya, H.; Jamison, T. F.* Angew. Chem. Int. Ed. 2008, 47, 1893.
14. Highly Selective Coupling of Alkenes and Aldehydes Catalyzed by NHC–Ni–P(OPh)3: Synergy Between a Strong σ-Donor and a Strong π-Acceptor.
Ho, C.-Y.; Jamison, T. F.* Angew. Chem. Int. Ed. 2007, 46, 782.
15. Nickel-Catalyzed Coupling of Alkenes, Aldehydes, and Silyl Triflates.
Ng, S.-S.; Ho, C.-Y.; Jamison, T. F.* J. Am. Chem. Soc. 2006, 128, 11513.
16. Nickel-Catalyzed, Carbonyl-Ene-Type Reactions: Selective for Alpha Olefins and More Efficient with Electron-Rich Aldehydes.
Ho, C.-Y.; Ng, S.-S.; Jamison, T. F.* J. Am. Chem. Soc. 2006, 128, 5326.
17. Nitrile assisted, Bronsted acid catalyzed regio and stereoselective diarylphosphonylation of allyl silyl ethers.
Ho, C.-Y.*; Chan, C.-W.; Wo, S.-K.; Zuo, Z.; Chan, L.-Y. Org. Biomol. Chem. 2010, 8, 3480.
18. Highly Chemoselective Reductive Amination of Carbonyl Compounds Promoted by InCl3/Et3SiH/MeOH System.
Lee, O.-Y.; Law, K.-L.; Ho, C.-Y.; Yang, D.* J. Org. Chem. 2008, 73, 8829
19. Fluorinated Chiral Secondary Amines as Catalysts for Epoxidation of Olefins with Oxone.
Ho, C.-Y.; Chen, Y.-C.; Wong, M.-K.; Yang, D.* J. Org. Chem. 2005, 70, 898.
20. Asymmetric epoxidation of olefins catalyzed by chiral iminium salts generated in-situ from chiral amines and aldehydes.
Wong, M.-K.; Ho, L.-M.; Zheng, Y.-S.; Ho, C.-Y.; Yang, D.* Org. Lett. 2001, 3, 2587.
21. Computational Exploration of Mechanism and Selectivities of NHC-Ni(II)hydride Catalyzed Hydroalkenylations of Styrene with a-Olefins.
Hong, X.; Wang, J.; Yang, Y.-F.; He, L.; Ho, C.-Y.*; Houk, K. N.* ACS Catal. 2015, 5, 5545.
22. Mechanism and Regioselectivities of (NHC)Nickel(II)hydride-Catalyzed Cycloisomerization of Dienes: A Computational Study.
Gao, Y.; Houk, K. N.; Ho, C.-Y.*; Hong, X.* Org. Biomol. Chem. 2017, 15, 7131.

1.一种支链烯丙基化合物的制备方法,何振宇,发明专利申请号:201480080767.8;申请日:2017.01.18

2.Process for preparing branched allyl compounds,何振宇,发明专利申请号:US-2017-0204032-A1,申请日:2017.01.07

3.process for preparing branched skipped dienes,何振宇,连小燕,陈伟豪,发明专利申请号:PCT/CN2017/085650,申请日:2017.05.24

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